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141.
Superfine graphite powder was prepared by ball-milling exfoliated graphite containing anhydrous CuCl2 in planetary ball milling systems. Nano-scale CuCl2 graphite intercalation compounds were synthesized by heating a mixture of anhydrous CuCl2 and graphite nanosheets. Scanning electron microscopy, energy-dispersive X-ray spectroscopy and high-resolution transmission electron microscopy were performed to characterize the microstructures of stage-1 nano-scale CuCl2 graphite intercalation compounds. The structure and components of the domain wall and core in the nano-scale CuCl2 graphite intercalation compounds are described. The results show that the content of CuCl2 in the mixture plays a crucial role in the size of the nano-scale CuCl2 graphite intercalation compound. 相似文献
142.
J. Kesselmeier 《Journal of Atmospheric Chemistry》2001,39(3):219-233
Field and laboratory investigations of the exchange of the short-chain organic acids – formic acid and acetic acid – as well as their homologous aldehydes are discussed. Both acids are substantially released from several plant species. Emission measurements under field conditions are compiled to give an overview of three years of measurements. Emission rates from several tree species were found in the range between zero and 60 nmoles m–2 min–1 for acetic acid and between zero and 90 nmoles m–2 min–1 for formic acid though also a deposition has been observed to orange trees. Investigations under laboratory conditions showed an order of magnitude lower emission rates with significant differences under light and dark conditions, and a deposition was observed under certain conditions. Hence, low emission rates or even a bi-directional exchange, emission as well as deposition have to be taken into account. Further differences between field and laboratory studies are discussed considering age of trees, stress effects and a potential production of acids by photochemical conversion of precursors inside enclosures during sampling. Field data on the exchange of form- and acetaldehyde show a complex behavior. We found emission as well as uptake. The bi-directional exchange is significantly triggered by the ambient mixing ratios of both aldehyde species and exhibits a compensation point. Further studies are needed for generalization of the exchange of these and potentially also for other compounds. 相似文献
143.
氢化物发生—原子荧光法直接测定锑及其化合物中的铅 总被引:1,自引:0,他引:1
通过在样品处理阶段用HBr除去大量锑基体,实现了不需再通过其他化学分离直接运用氢化物发生-原子荧光法测定锑及其相关产品中的微量铅,并用于实际样品的分析.该方法对样品检测下限小于10-6,在实际样品分析中,分析结果与原子吸收法测定结果之间无显著性差异,RSD<2.0%(n=4),对样品分析的加标回收率在95%~105%. 相似文献
144.
胜利油田孤岛原油中有机硅化合物的发现及其石油地质意义 总被引:7,自引:0,他引:7
采用溶剂萃取法从胜利油田孤岛原油中分离得到浓缩的含氧化合物,再用柱色谱分离得到有机硅及其它组分。用红外、电子能谱、气相色谱-质谱法分离鉴定了有机硅组分。鉴定出的有机硅化合物有硅Si3-Si7的甲基硅氧烷和Si3-Si5的环甲基硅氧烷以及三甲基硅的衍生物。资料表明:在高等和低等生物体中还不能肯定含有Si-C键的有机化合物。因此,原油中有机硅化合物的发现是原油无机成因的一个证据。本文还简要讨论了位于勃海湾盆地孤岛原油的无机成因的地质环境及其石油地质意义。 相似文献
145.
有机累托石的合成与特性研究 总被引:7,自引:0,他引:7
累托石是二八面体云母层与蒙脱石层1:1规间民支矿物,兼有云母和蒙脱三 某些特征。本文利用二甲基十八烷基羟乙基季铵盐与累托石进行阳离子交换反应合成有机累托石。并采用物理化学、X射线衍射、差热、热失重和红外吸收光谱等分析方法对它的特性进行了研究。经季铵盐复合处理后,累托放扣蒙脱石层间被有机阳离子覆盖,它的面网间距d001由原来的24.8°/A增至29.5°/A。累托石粘土亲水憎油性转变为憎水亲油性有机粘土后能在有机溶剂中膨胀和分散。它是一种有应用前景的新材料。 相似文献
146.
147.
S. Derenne C. Largeau E. Casadevall J.S. Sinninghe Damst E.W. Tegelaar J.W. de Leeuw 《Organic Geochemistry》1990,16(4-6)
The kerogen of a sample of Estonian Kukersite (Ordovician) was examined by spectroscopic (solid state 13C NMR, FTIR) and pyrolytic (“off-line”, flash) methods. This revealed an important contribution of long, linear alkyl chains in Kukersite kerogen. The hydrocarbons formed upon pyrolysis are dominated by n-alkanes and n-alk-1-enes and probably reflect a major contribution of selectivity preserved, highly aliphatic, resistant biomacromolecules from the outer cell walls of Gloeocapsomorpha prisca. This is consistent with the abundant presence of this fossilized organism in Kukersite kerogen. In addition high amounts of phenolic compounds were identified in the pyrolysates. Series of non-methylated, mono-, di- and trimethylated 3-n-alkylphenols, 5-n-alkyl-1,3-benzenediols and n-alkylhydroxybenzofurans were identified. All series of phenolic compounds contain long (up to C19), linear alkyl side-chains. Kukersite kerogen is, therefore, an aliphatic type II/I kerogen, despite the abundance of free phenolic moieties. This study shows that phenol-derived moieties are not necessarily associated with higher plant-derived organic matter.The flash pyrolysate of Kukersite kerogen was also compared with that of the kerogen of the Guttenberg Oil Rock (Ordovician) which is also composed of accumulations of fossilized G. prisca. Similarities in the distributions of hydrocarbons and sulphur compounds were noted, especially for the C1–C6 alkylbenzene and alkylthiophene distributions. However, no phenolic compounds were detected in the flash pyrolysate of the Guttenberg kerogen. Possible explanations for the observed similarities and differences are discussed. 相似文献
148.
本文讨论以工业KCI和NH4HCO3为原料、采用离子交换法(国产732钠型树脂)生产K2CO3的工艺。小试验的结果:以20%KCI溶液上柱,以分段交换率在50%以前为穿漏点、流速为0.033(ml/min.ml树脂)时,总交换率达83.3%,工作交换容量达2.24(毫摩尔钾/ml树脂);当以饱和NH4HCO3溶液进行解脱、流速在0.033(ml/min.ml树脂)时,解脱率达91.8%,产品的含量为98.2%。 相似文献
149.
从松节藻中分离的含卤素化合物表现出显著PTP1B抑制活性。其中BPN效果最佳。为研究BPN侧链基团极性对其抑制活性的影响,本文以香兰素(1)为起始原料,经过溴代、氧化、还原、傅克烷基化以及酯化等反应,成功合成了新化合物2,3-二溴-1-(2-溴-3,4-二甲氧基-6-((4-硝基苯氧基)甲基)苯甲基)-4,5-二甲氧基苯(10)、4-((3-溴-2-(2,3-二溴-4,5-二甲氧基苄基)-4,5-二甲氧基苄基)醚)苯胺(11)、4-((3-溴-2-(2,3-二溴-4,5-二甲氧基苄基)-4,5-二甲氧基苄基)醚)-4-乙酰乙酸(12)和3-溴-2-(2,3-二溴-4,5-二甲氧基苄基)-4,5-二甲氧基苯甲醛肟(14)。通过1 H-NMR,13C-NMR等方法对目标产物进行了结构表征。并对化合物进行了PTP1B酶抑制活性的测定,结果表明化合物侧链极性对PTP1B酶抑制活性有显著影响。 相似文献
150.